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・ Diphasiastrum digitatum
・ Diphasiastrum sitchense
・ Diphasiastrum tristachyum
・ Diphasiastrum × issleri
・ Diphasiastrum × sabinifolium
・ Diphemanil metilsulfate
・ Diphenadione
・ Diphenhydramine
・ Diphenidine
・ Diphenidol
・ Diphenol
・ Diphenolic acid
・ Diphenoxylate
・ Diphenyl carbonate
・ Diphenyl diselenide
Diphenyl disulfide
・ Diphenyl ditelluride
・ Diphenyl ether
・ Diphenyl oxalate
・ Diphenyl sulfone
・ Diphenyl-2-pyridylmethane
・ Diphenyl-2-pyridylphosphine
・ Diphenylacetylene
・ Diphenylalanine
・ Diphenylamine
・ Diphenylamine (data page)
・ Diphenylbutylpiperidine
・ Diphenylchlorarsine
・ Diphenylcyanoarsine
・ Diphenylcyclopropenone


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Diphenyl disulfide : ウィキペディア英語版
Diphenyl disulfide

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Diphenyl disulfide is the chemical compound with the formula (C6H5S)2. This colorless crystalline material is often abbreviated Ph2S2. It is one of the most popular organic disulfides used in organic synthesis. Minor contamination by thiophenol is responsible for the disagreeable odour associated with this compound.
==Preparation and structure==
Ph2S2 is usually prepared by the oxidation of thiophenol:
: 2 PhSH + I2 → Ph2S2 + 2 HI
Hydrogen peroxide can also be used as the oxidant. Ph2S2 is rarely prepared in the laboratory because it is inexpensive, and the precursor has a disagreeable odour.
Like most organic disulfides, the C2S2 core of Ph2S2 is non-planar with a dihedral angle approaching 85°.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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